Per- and polyfluoroalkyl substances (PFAS) are widespread in the environment, as a result of decades of use across a range of applications. While PFAS contamination often enters the environment in the aqueous phase, PFAS is regularly detected in a range of different phases, including soils, sediments and biota. Although PFAS at a given site may originate from the same sources, the compositions observed in different phases are nearly always different, a fact that can complicate source allocation efforts. This paper presents a quantitative method for prediction of the relative composition of PFAS in different phases for components for which differences in behavior are primarily driven by hydrophobicity. The derived equations suggest that under these conditions, the relative compositions in different phases in contact with water should be independent of overall affinity for the phase, and as such should be the same for all non-water phases. This result is illustrated with data from individual samples, as well as from site-wide evaluations for a range of different phases. The results of the work provide a useful tool to reconcile PFAS composition differences in different phases, and provide a baseline for recognizing cases where hydrophobicity is not the primary driver of differences in distribution between phases. Furthermore, the results may be useful in forensic applications for classification of PFAS across different phases. The use of the resulting equations to transform water data to train a supervised learning algorithm for forensic analysis of PFAS in non-water phases is illustrated.To investigate mercury (Hg) sources responsible for contamination at Gumu Creek in South Korea, Hg concentration (THg) and Hg isotope ratios were measured in the soil and sediment of Gumu Creek and the samples from a hazardous waste landfill (HWL). The THg ranged between 0.29-327 mg kg-1 and 9.5-414 mg kg-1 in the soil and sediment, respectively, reflecting heterogeneous distribution and elevated levels across the entire Gumu Creek. Without the soil with the lowest THg (0.30 ± 0.01 mg kg-1, n = 3), the δ202Hg (-0.83 to -0.18‰) and Δ199Hg (-0.24 to 0.01‰) of the sediment and soil of Gumu Creek were within the ranges of the HWL samples (δ202Hg; -1.29 to -0.38‰, Δ199Hg; -0.31 to 0.01‰). The comparison with the literature reporting sediment Hg isotope ratios impacted by various anthropogenic Hg sources revealed a presence of diverse Hg sources at Gumu Creek, including commercial liquid Hg, phenyl-Hg, and fly ash, consistent with the types of waste deposited within the HWL. Using commercial liquid Hg, fly ash, and the soil with the lowest THg as end-members, the ternary mixing model yielded 25-88% and 12-57% contributions from commercial liquid Hg and fly ash to the Gumu Creek sediment, respectively. The results of our study suggest that Hg isotope ratios are an effective tool for screening potential Hg sources at sites where the distribution of Hg is heterogeneous and multiple anthropogenic activities exist.The fertilization using sewage sludge (SS) and/or SS-derived products have been extensively studied and known to increase crop yield as soil nutrients and plant growth are improved. This study aimed to evaluate two SS application methods (i.e. mulching and mixing with the soil) on soil fertility parameters and the productivity of cereal crops. It compared the effect of SS fertilization methods on changes in soil physicochemical parameters in order to highlight the application mode which gives the best agronomic values and sustains soil productivity. Foliar surface, grain starch content and grain yield of durum wheat (Triticum durum) were determined in plants grown in plastic planters for different fertilization treatments (SS-mulched, SS-mixed, urea, and unfertilized). Each SS treatment was applied in three levels (SS1 = 1% w/w ratio, SS2 = 4%, SS3 = 8.3%). The application of SS improved all soil properties compared to the control and urea, with the SS mulching treatment was the best. The significant improvement of soil fertility was confirmed by soil CP ratio which indicated a good soil mineralization status, in particular under the screen formed by mulching that helped to conserve high soil moisture for optimizing plant growth. Soil calcium accumulated in greater amount in biosolid-soil mixtures than in SS-mulched soils. https://www.selleckchem.com/products/ag-221-enasidenib.html Regardless of SS doses, the highest crop grain yields were obtained with the SS mulch treatments. Mulching SS, compared to SS-mixed soils, brings better results in terms of improving soil fertility and yielding high productions. The applicable of this method is also easy in the field and/or large-scale cultures.In this study, calcite was investigated as an activator for the norfloxacin (NOR) degradation by peroxymonosulfate (PMS). Under optimum conditions, the NOR removal percentage was 99.7% within 60 min, and the pseudo-first-order kinetics effectively described the two-stage oxidation process. The NOR removal percentage improved from 10.4% to 91.5% and the reaction rate constant elevated from 0.0010 to 0.1217 min-1 when 0.5 g/L calcite was added compared to that without calcite addition. Furthermore, the results of radical scavenger and electron spin resonance trapping indicated that the favorable alkaline environment and a proper level of carbonate in the Calcite/PMS system facilitated the activation of PMS to generate 1O2 for rapid NOR degradation. Compared with NaOH, calcite was able to maintain the pH (8-9) of the reaction system stable. Besides, the content of anions with buffering capacity and organic matter in the water matrix influenced the removal percentage of NOR. Seven intermediates were identified and the NOR degradation pathways were suggested. The findings of this research provided an environmentally friendly activator for remediation of organic wastewater and deepened the understanding of the interaction between calcium carbonate and PMS.Dwarf bamboo is a woody plant with potential for use in the remediation of Pb-contaminated soil. Due to its clonal growth habit, there are two keys to its application for continuous soil Pb remediation 1) its ability to form shoots and grow into new bamboo normally under Pb stress and 2) the Pb tolerance and accumulation characteristics of this new bamboo. Here, 5 species of dwarf bamboo were treated with 2 levels of soil Pb stress (0 and 1500 mg kg-1). In the roots of 3 of the species (Sasa argenteostriata, Sasaella glabra, and Indocalamus decorus), Pb tended to be distributed along the cell wall and transported to vacuoles. In the other 2 species (Sasa auricoma and Sasa fortunei), Pb was arranged linearly along the cell wall. Under Pb treatment, the new bamboo of all species showed gradual physiological adaptation to Pb stress. Correlations of the net photosynthetic rate, superoxide dismutase activity, and free proline levels with Pb content in new leaves in November were all higher than those in July, though that of malondialdehyde content decreased, suggesting that new dwarf bamboo exhibits good soil Pb stress tolerance.